CCL:G: REPLY TO Johannes Poms severe error message 2070 - input/error log



 Sent to CCL by: "Enrico  D Ortenzio" [enrico.dortenzio]^[hotmail.it]
 Entering Link 1 = C:\G03W\l1.exe PID=      2392.
  Copyright (c) 1988,1990,1992,1993,1995,1998,2003, Gaussian, Inc.
                   All Rights Reserved.
  This is the Gaussian(R) 03 program.  It is based on the
  the Gaussian(R) 98 system (copyright 1998, Gaussian, Inc.),
  the Gaussian(R) 94 system (copyright 1995, Gaussian, Inc.),
  the Gaussian 92(TM) system (copyright 1992, Gaussian, Inc.),
  the Gaussian 90(TM) system (copyright 1990, Gaussian, Inc.),
  the Gaussian 88(TM) system (copyright 1988, Gaussian, Inc.),
  the Gaussian 86(TM) system (copyright 1986, Carnegie Mellon
  University), and the Gaussian 82(TM) system (copyright 1983,
  Carnegie Mellon University). Gaussian is a federally registered
  trademark of Gaussian, Inc.
  This software contains proprietary and confidential information,
  including trade secrets, belonging to Gaussian, Inc.
  This software is provided under written license and may be
  used, copied, transmitted, or stored only in accord with that
  written license.
  The following legend is applicable only to US Government
  contracts under DFARS:
                     RESTRICTED RIGHTS LEGEND
  Use, duplication or disclosure by the US Government is subject
  to restrictions as set forth in subparagraph (c)(1)(ii) of the
  Rights in Technical Data and Computer Software clause at DFARS
  252.227-7013.
  Gaussian, Inc.
  Carnegie Office Park, Building 6, Pittsburgh, PA 15106 USA
  The following legend is applicable only to US Government
  contracts under FAR:
                     RESTRICTED RIGHTS LEGEND
  Use, reproduction and disclosure by the US Government is subject
  to restrictions as set forth in subparagraph (c) of the
  Commercial Computer Software - Restricted Rights clause at FAR
  52.227-19.
  Gaussian, Inc.
  Carnegie Office Park, Building 6, Pittsburgh, PA 15106 USA
  ---------------------------------------------------------------
  Warning -- This program may not be used in any manner that
  competes with the business of Gaussian, Inc. or will provide
  assistance to any competitor of Gaussian, Inc.  The licensee
  of this program is prohibited from giving any competitor of
  Gaussian, Inc. access to this program.  By using this program,
  the user acknowledges that Gaussian, Inc. is engaged in the
  business of creating and licensing software in the field of
  computational chemistry and represents and warrants to the
  licensee that it is not a competitor of Gaussian, Inc. and that
  it will not use this program in any manner prohibited above.
  ---------------------------------------------------------------
  Cite this work as:
  Gaussian 03, Revision B.01,
  M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria,
  M. A. Robb, J. R. Cheeseman, J. A. Montgomery, Jr., T. Vreven,
  K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi,
  V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega,
  G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota,
  R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao,
  H. Nakai, M. Klene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross,
  C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev,
  A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, P. Y. Ayala,
  K. Morokuma, G. A. Voth, P. Salvador, J. J. Dannenberg,
  V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain,
  O. Farkas, D. K. Malick, A. D. Rabuck, K. Raghavachari,
  J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, S. Clifford,
  J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz,
  I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham,
  C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill,
  B. Johnson, W. Chen, M. W. Wong, C. Gonzalez, and J. A. Pople,
  Gaussian, Inc., Pittsburgh PA, 2003.
  *********************************************
  Gaussian 03:  x86-Win32-G03RevB.01 3-Mar-2003
                   30-Dec-2011
  *********************************************
  %chk=C:\Users\Enrico D\Desktop\Gaussian\Results\iRIDIUM OLED1.chk
  Default route:  MaxDisk=4gb
  -----------------------------------
  # opt b3lyp/3-21g geom=connectivity
  -----------------------------------
  1/14=-1,18=20,26=3,38=1,57=2/1,3;
  2/9=110,17=6,18=5,40=1/2;
  3/5=5,11=2,16=1,25=1,30=1,74=-5/1,2,3;
  4//1;
  5/5=2,38=5/2;
  6/7=2,8=2,9=2,10=2,28=1/1;
  7//1,2,3,16;
  1/14=-1,18=20/3(1);
  99//99;
  2/9=110/2;
  3/5=5,11=2,16=1,25=1,30=1,74=-5/1,2,3;
  4/5=5,16=3/1;
  5/5=2,38=5/2;
  7//1,2,3,16;
  1/14=-1,18=20/3(-5);
  2/9=110/2;
  6/7=2,8=2,9=2,10=2,19=2,28=1/1;
  99/9=1/99;
  ----------------
  iRIDIUM OLED.mol
  ----------------
  Symbolic Z-matrix:
  Charge =  0 Multiplicity = 1
  C                    -5.3806    2.6323   -1.9424
  C                    -5.0324    1.5169   -1.2458
  C                    -3.5598    1.0948   -1.221
  C                    -2.6222    1.7957   -1.9066
  C                    -2.9988    3.0666   -2.6769
  C                    -4.3005    3.4627   -2.6872
  C                    -3.0125   -0.1194   -0.4335
  C                    -3.7516   -0.9662    0.3189
  C                    -3.018    -2.099     1.0668
  C                    -1.6673   -2.1971    0.9585
  C                    -0.9071   -1.1922    0.0749
  N                    -1.5692   -0.283    -0.5554
  C                    -1.6034    3.4927   -0.5875
  C                    -2.4835   -1.4536   -2.759
  N                    -0.6297    2.6399   -0.7019
  C                     0.648     2.8509   -0.0432
  C                     0.9131    3.9638    0.6714
  C                    -0.1967    5.0191    0.8168
  C                    -1.398     4.7882    0.23
  C                    -2.9235   -2.3121   -3.7166
  C                    -2.3584   -2.2239   -5.1545
  C                    -1.4177   -1.2904   -5.4625
  C                    -0.9371   -0.3301   -4.3637
  C                    -1.4359   -0.3895   -3.1227
  C                     1.6077    1.6899   -0.2413
  C                     0.1143    0.7455   -4.5487
  C                     0.7753    0.985    -5.702
  C                     1.8606    2.0715   -5.7009
  C                     2.1046    2.7522   -4.5538
  C                     1.2782    2.4254   -3.2838
  N                     0.3631    1.5009   -3.3292
  C                     1.9577   -0.5534   -1.2793
  C                     1.1158    0.7065   -1.0171
  C                     3.194    -0.658    -0.7151
  C                     3.7517    0.4846    0.1653
  C                     3.0064    1.599     0.3812
  Ir                   -0.764     0.995    -1.7816
  H                    -6.4052    2.9376   -1.9769
  H                    -5.7724    0.9449   -0.7241
  H                    -2.2524    3.6305   -3.1929
  H                    -4.5819    4.35     -3.213
  H                    -4.8122   -0.8543    0.3924
  H                    -3.5633   -2.7945    1.664
  H                    -1.1363   -2.9652    1.4801
  H                     0.1587   -1.2457   -0.0217
  H                    -2.5438    3.3019   -1.0613
  H                    -2.8668   -1.516    -1.7617
  H                     1.8712    4.112     1.1266
  H                    -0.0262    5.9172    1.3739
  H                    -2.1965    5.4957    0.3319
  H                    -3.661    -3.0499   -3.4775
  H                    -2.7108   -2.8947   -5.9079
  H                    -1.0189   -1.2296   -6.4552
  H                     0.5501    0.4312   -6.5926
  H                     2.4161    2.2856   -6.5886
  H                     2.8611    3.5083   -4.5265
  H                     1.4598    2.9586   -2.3778
  H                     1.5784   -1.3403   -1.8977
  H                     3.7829   -1.5386   -0.8807
  H                     4.7258    0.3981    0.6037
  H                     3.3872    2.3995    0.9821
  GradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGrad
  Berny optimization.
  Initialization pass.
                            ----------------------------
                            !    Initial Parameters    !
                            ! (Angstroms and Degrees)  !
  --------------------------                            ----------------------
 ----
  ! Name  Definition              Value          Derivative Info.
 !
  ----------------------------------------------------------------------------
 ----
  ! R1    R(1,2)                  1.3604         estimate D2E/DX2
 !
  ! R2    R(1,6)                  1.5527         estimate D2E/DX2
 !
  ! R3    R(1,38)                 1.0697         estimate D2E/DX2
 !
  ! R4    R(2,3)                  1.5321         estimate D2E/DX2
 !
  ! R5    R(2,39)                 1.071          estimate D2E/DX2
 !
  ! R6    R(3,4)                  1.3566         estimate D2E/DX2
 !
  ! R7    R(3,7)                  1.5472         estimate D2E/DX2
 !
  ! R8    R(4,5)                  1.5331         estimate D2E/DX2
 !
  ! R9    R(4,37)                 2.0272         estimate D2E/DX2
 !
  ! R10   R(5,6)                  1.3607         estimate D2E/DX2
 !
  ! R11   R(5,40)                 1.0683         estimate D2E/DX2
 !
  ! R12   R(5,46)                 1.6949         estimate D2E/DX2
 !
  ! R13   R(6,41)                 1.0691         estimate D2E/DX2
 !
  ! R14   R(7,8)                  1.3526         estimate D2E/DX2
 !
  ! R15   R(7,12)                 1.4576         estimate D2E/DX2
 !
  ! R16   R(7,47)                 1.9328         estimate D2E/DX2
 !
  ! R17   R(8,9)                  1.543          estimate D2E/DX2
 !
  ! R18   R(8,42)                 1.069          estimate D2E/DX2
 !
  ! R19   R(9,10)                 1.3586         estimate D2E/DX2
 !
  ! R20   R(9,43)                 1.0666         estimate D2E/DX2
 !
  ! R21   R(10,11)                1.539          estimate D2E/DX2
 !
  ! R22   R(10,44)                1.0696         estimate D2E/DX2
 !
  ! R23   R(11,12)                1.2893         estimate D2E/DX2
 !
  ! R24   R(11,45)                1.0715         estimate D2E/DX2
 !
  ! R25   R(12,37)                1.9456         estimate D2E/DX2
 !
  ! R26   R(13,15)                1.2994         estimate D2E/DX2
 !
  ! R27   R(13,19)                1.5456         estimate D2E/DX2
 !
  ! R28   R(13,46)                1.0702         estimate D2E/DX2
 !
  ! R29   R(14,20)                1.3593         estimate D2E/DX2
 !
  ! R30   R(14,24)                1.5369         estimate D2E/DX2
 !
  ! R31   R(14,47)                1.0702         estimate D2E/DX2
 !
  ! R32   R(15,16)                1.4529         estimate D2E/DX2
 !
  ! R33   R(15,37)                1.9722         estimate D2E/DX2
 !
  ! R34   R(16,17)                1.3489         estimate D2E/DX2
 !
  ! R35   R(16,25)                1.5193         estimate D2E/DX2
 !
  ! R36   R(17,18)                1.5383         estimate D2E/DX2
 !
  ! R37   R(17,48)                1.071          estimate D2E/DX2
 !
  ! R38   R(18,19)                1.3568         estimate D2E/DX2
 !
  ! R39   R(18,49)                1.0705         estimate D2E/DX2
 !
  ! R40   R(19,50)                1.0717         estimate D2E/DX2
 !
  ! R41   R(20,21)                1.5475         estimate D2E/DX2
 !
  ! R42   R(20,51)                1.0702         estimate D2E/DX2
 !
  ! R43   R(21,22)                1.3606         estimate D2E/DX2
 !
  ! R44   R(21,52)                1.0685         estimate D2E/DX2
 !
  ! R45   R(22,23)                1.5364         estimate D2E/DX2
 !
  ! R46   R(22,53)                1.0715         estimate D2E/DX2
 !
  ! R47   R(23,24)                1.3388         estimate D2E/DX2
 !
  ! R48   R(23,26)                1.5154         estimate D2E/DX2
 !
  ! R49   R(24,37)                2.0413         estimate D2E/DX2
 !
  ! R50   R(25,33)                1.3457         estimate D2E/DX2
 !
  ! R51   R(25,36)                1.5337         estimate D2E/DX2
 !
  ! R52   R(26,27)                1.3507         estimate D2E/DX2
 !
  ! R53   R(26,31)                1.4559         estimate D2E/DX2
 !
  ! R54   R(27,28)                1.5357         estimate D2E/DX2
 !
  ! R55   R(27,54)                1.0726         estimate D2E/DX2
 !
  ! R56   R(28,29)                1.356          estimate D2E/DX2
 !
  ! R57   R(28,55)                1.0688         estimate D2E/DX2
 !
  ! R58   R(29,30)                1.55           estimate D2E/DX2
 !
  ! R59   R(29,56)                1.0699         estimate D2E/DX2
 !
  ! R60   R(30,31)                1.3016         estimate D2E/DX2
 !
  ! R61   R(30,57)                1.0668         estimate D2E/DX2
 !
  ! R62   R(31,37)                1.9802         estimate D2E/DX2
 !
  ! R63   R(32,33)                1.5378         estimate D2E/DX2
 !
  ! R64   R(32,34)                1.363          estimate D2E/DX2
 !
  ! R65   R(32,58)                1.0703         estimate D2E/DX2
 !
  ! R66   R(33,37)                2.0497         estimate D2E/DX2
 !
  ! R67   R(34,35)                1.5465         estimate D2E/DX2
 !
  ! R68   R(34,59)                1.0722         estimate D2E/DX2
 !
  ! R69   R(35,36)                1.3579         estimate D2E/DX2
 !
  ! R70   R(35,60)                1.0717         estimate D2E/DX2
 !
  ! R71   R(36,61)                1.0709         estimate D2E/DX2
 !
  ! A1    A(2,1,6)              120.4028         estimate D2E/DX2
 !
  ! A2    A(2,1,38)             119.7164         estimate D2E/DX2
 !
  ! A3    A(6,1,38)             119.8808         estimate D2E/DX2
 !
  ! A4    A(1,2,3)              118.6984         estimate D2E/DX2
 !
  ! A5    A(1,2,39)             120.6975         estimate D2E/DX2
 !
  ! A6    A(3,2,39)             120.6041         estimate D2E/DX2
 !
  ! A7    A(2,3,4)              120.9153         estimate D2E/DX2
 !
  ! A8    A(2,3,7)              124.3625         estimate D2E/DX2
 !
  ! A9    A(4,3,7)              114.7205         estimate D2E/DX2
 !
  ! A10   A(3,4,5)              120.8268         estimate D2E/DX2
 !
  ! A11   A(3,4,37)             113.4707         estimate D2E/DX2
 !
  ! A12   A(5,4,37)             125.702          estimate D2E/DX2
 !
  ! A13   A(4,5,6)              118.6936         estimate D2E/DX2
 !
  ! A14   A(4,5,40)             120.5715         estimate D2E/DX2
 !
  ! A15   A(6,5,40)             120.7347         estimate D2E/DX2
 !
  ! A16   A(1,6,5)              120.4083         estimate D2E/DX2
 !
  ! A17   A(1,6,41)             119.7809         estimate D2E/DX2
 !
  ! A18   A(5,6,41)             119.8107         estimate D2E/DX2
 !
  ! A19   A(3,7,8)              125.5309         estimate D2E/DX2
 !
  ! A20   A(3,7,12)             113.3131         estimate D2E/DX2
 !
  ! A21   A(8,7,12)             121.1523         estimate D2E/DX2
 !
  ! A22   A(7,8,9)              117.9999         estimate D2E/DX2
 !
  ! A23   A(7,8,42)             120.9875         estimate D2E/DX2
 !
  ! A24   A(9,8,42)             121.0126         estimate D2E/DX2
 !
  ! A25   A(8,9,10)             119.1476         estimate D2E/DX2
 !
  ! A26   A(8,9,43)             120.4666         estimate D2E/DX2
 !
  ! A27   A(10,9,43)            120.3855         estimate D2E/DX2
 !
  ! A28   A(9,10,11)            119.3219         estimate D2E/DX2
 !
  ! A29   A(9,10,44)            120.4347         estimate D2E/DX2
 !
  ! A30   A(11,10,44)           120.2434         estimate D2E/DX2
 !
  ! A31   A(10,11,12)           119.1749         estimate D2E/DX2
 !
  ! A32   A(10,11,45)           120.6965         estimate D2E/DX2
 !
  ! A33   A(12,11,45)           120.1282         estimate D2E/DX2
 !
  ! A34   A(7,12,11)            123.1438         estimate D2E/DX2
 !
  ! A35   A(7,12,37)            112.8782         estimate D2E/DX2
 !
  ! A36   A(11,12,37)           123.9731         estimate D2E/DX2
 !
  ! A37   A(15,13,19)           119.8079         estimate D2E/DX2
 !
  ! A38   A(15,13,46)           120.165          estimate D2E/DX2
 !
  ! A39   A(19,13,46)           120.0265         estimate D2E/DX2
 !
  ! A40   A(20,14,24)           119.421          estimate D2E/DX2
 !
  ! A41   A(20,14,47)           120.2466         estimate D2E/DX2
 !
  ! A42   A(24,14,47)           120.3318         estimate D2E/DX2
 !
  ! A43   A(13,15,16)           121.5845         estimate D2E/DX2
 !
  ! A44   A(13,15,37)           122.9947         estimate D2E/DX2
 !
  ! A45   A(16,15,37)           115.4178         estimate D2E/DX2
 !
  ! A46   A(15,16,17)           122.1973         estimate D2E/DX2
 !
  ! A47   A(15,16,25)           112.6696         estimate D2E/DX2
 !
  ! A48   A(17,16,25)           125.1292         estimate D2E/DX2
 !
  ! A49   A(16,17,18)           118.3124         estimate D2E/DX2
 !
  ! A50   A(16,17,48)           121.0061         estimate D2E/DX2
 !
  ! A51   A(18,17,48)           120.6815         estimate D2E/DX2
 !
  ! A52   A(17,18,19)           118.7603         estimate D2E/DX2
 !
  ! A53   A(17,18,49)           120.6506         estimate D2E/DX2
 !
  ! A54   A(19,18,49)           120.5887         estimate D2E/DX2
 !
  ! A55   A(13,19,18)           119.2802         estimate D2E/DX2
 !
  ! A56   A(13,19,50)           120.3064         estimate D2E/DX2
 !
  ! A57   A(18,19,50)           120.4134         estimate D2E/DX2
 !
  ! A58   A(14,20,21)           120.0268         estimate D2E/DX2
 !
  ! A59   A(14,20,51)           120.0711         estimate D2E/DX2
 !
  ! A60   A(21,20,51)           119.9022         estimate D2E/DX2
 !
  ! A61   A(20,21,22)           120.1277         estimate D2E/DX2
 !
  ! A62   A(20,21,52)           119.9297         estimate D2E/DX2
 !
  ! A63   A(22,21,52)           119.9421         estimate D2E/DX2
 !
  ! A64   A(21,22,23)           118.8954         estimate D2E/DX2
 !
  ! A65   A(21,22,53)           120.3955         estimate D2E/DX2
 !
  ! A66   A(23,22,53)           120.7089         estimate D2E/DX2
 !
  ! A67   A(22,23,24)           121.2422         estimate D2E/DX2
 !
  ! A68   A(22,23,26)           124.9835         estimate D2E/DX2
 !
  ! A69   A(24,23,26)           113.7742         estimate D2E/DX2
 !
  ! A70   A(14,24,23)           120.2671         estimate D2E/DX2
 !
  ! A71   A(14,24,37)           122.5808         estimate D2E/DX2
 !
  ! A72   A(23,24,37)           117.1464         estimate D2E/DX2
 !
  ! A73   A(16,25,33)           113.7478         estimate D2E/DX2
 !
  ! A74   A(16,25,36)           124.6431         estimate D2E/DX2
 !
  ! A75   A(33,25,36)           121.6044         estimate D2E/DX2
 !
  ! A76   A(23,26,27)           124.7231         estimate D2E/DX2
 !
  ! A77   A(23,26,31)           112.6166         estimate D2E/DX2
 !
  ! A78   A(27,26,31)           122.6545         estimate D2E/DX2
 !
  ! A79   A(26,27,28)           118.0791         estimate D2E/DX2
 !
  ! A80   A(26,27,54)           120.974          estimate D2E/DX2
 !
  ! A81   A(28,27,54)           120.9468         estimate D2E/DX2
 !
  ! A82   A(27,28,29)           118.877          estimate D2E/DX2
 !
  ! A83   A(27,28,55)           120.5585         estimate D2E/DX2
 !
  ! A84   A(29,28,55)           120.5642         estimate D2E/DX2
 !
  ! A85   A(28,29,30)           119.4286         estimate D2E/DX2
 !
  ! A86   A(28,29,56)           120.2363         estimate D2E/DX2
 !
  ! A87   A(30,29,56)           120.335          estimate D2E/DX2
 !
  ! A88   A(29,30,31)           119.7359         estimate D2E/DX2
 !
  ! A89   A(29,30,57)           119.9793         estimate D2E/DX2
 !
  ! A90   A(31,30,57)           120.2847         estimate D2E/DX2
 !
  ! A91   A(26,31,30)           121.1905         estimate D2E/DX2
 !
  ! A92   A(26,31,37)           115.1377         estimate D2E/DX2
 !
  ! A93   A(30,31,37)           123.6666         estimate D2E/DX2
 !
  ! A94   A(33,32,34)           119.2669         estimate D2E/DX2
 !
  ! A95   A(33,32,58)           120.4544         estimate D2E/DX2
 !
  ! A96   A(34,32,58)           120.2788         estimate D2E/DX2
 !
  ! A97   A(25,33,32)           119.7939         estimate D2E/DX2
 !
  ! A98   A(25,33,37)           116.5769         estimate D2E/DX2
 !
  ! A99   A(32,33,37)           123.6281         estimate D2E/DX2
 !
  ! A100  A(32,34,35)           120.4016         estimate D2E/DX2
 !
  ! A101  A(32,34,59)           119.8201         estimate D2E/DX2
 !
  ! A102  A(35,34,59)           119.7781         estimate D2E/DX2
 !
  ! A103  A(34,35,36)           119.9281         estimate D2E/DX2
 !
  ! A104  A(34,35,60)           120.0676         estimate D2E/DX2
 !
  ! A105  A(36,35,60)           120.0042         estimate D2E/DX2
 !
  ! A106  A(25,36,35)           118.99           estimate D2E/DX2
 !
  ! A107  A(25,36,61)           120.5127         estimate D2E/DX2
 !
  ! A108  A(35,36,61)           120.4961         estimate D2E/DX2
 !
  ! A109  A(4,37,12)             85.3513         estimate D2E/DX2
 !
  ! A110  A(4,37,15)             76.5114         estimate D2E/DX2
 !
  ! A111  A(4,37,24)             85.7372         estimate D2E/DX2
 !
  ! A112  A(4,37,31)            111.8774         estimate D2E/DX2
 !
  ! A113  A(4,37,33)            156.8132         estimate D2E/DX2
 !
  ! A114  A(12,37,15)           103.3567         estimate D2E/DX2
 !
  ! A115  A(12,37,24)            80.3468         estimate D2E/DX2
 !
  ! A116  A(12,37,31)           153.6289         estimate D2E/DX2
 !
  ! A117  A(12,37,33)            92.9824         estimate D2E/DX2
 !
  ! A118  A(15,37,24)           161.4038         estimate D2E/DX2
 !
  ! A119  A(15,37,31)           100.1379         estimate D2E/DX2
 !
  ! A120  A(15,37,33)            81.4165         estimate D2E/DX2
 !
  ! A121  A(24,37,31)            81.2091         estimate D2E/DX2
 !
  ! A122  A(24,37,33)           116.8366         estimate D2E/DX2
 !
  ! A123  A(31,37,33)            78.7821         estimate D2E/DX2
 !
  ! D1    D(6,1,2,3)             -0.4324         estimate D2E/DX2
 !
  ! D2    D(6,1,2,39)           179.5235         estimate D2E/DX2
 !
  ! D3    D(38,1,2,3)           179.5284         estimate D2E/DX2
 !
  ! D4    D(38,1,2,39)           -0.5156         estimate D2E/DX2
 !
  ! D5    D(2,1,6,5)              1.5265         estimate D2E/DX2
 !
  ! D6    D(2,1,6,41)          -178.6023         estimate D2E/DX2
 !
  ! D7    D(38,1,6,5)          -178.4343         estimate D2E/DX2
 !
  ! D8    D(38,1,6,41)            1.4368         estimate D2E/DX2
 !
  ! D9    D(1,2,3,4)             -1.6877         estimate D2E/DX2
 !
  ! D10   D(1,2,3,7)            177.8283         estimate D2E/DX2
 !
  ! D11   D(39,2,3,4)           178.3563         estimate D2E/DX2
 !
  ! D12   D(39,2,3,7)            -2.1277         estimate D2E/DX2
 !
  ! D13   D(2,3,4,5)              2.6934         estimate D2E/DX2
 !
  ! D14   D(2,3,4,37)          -177.5269         estimate D2E/DX2
 !
  ! D15   D(7,3,4,5)           -176.8667         estimate D2E/DX2
 !
  ! D16   D(7,3,4,37)             2.913          estimate D2E/DX2
 !
  ! D17   D(2,3,7,8)              0.597          estimate D2E/DX2
 !
  ! D18   D(2,3,7,12)          -178.7095         estimate D2E/DX2
 !
  ! D19   D(4,3,7,8)           -179.8602         estimate D2E/DX2
 !
  ! D20   D(4,3,7,12)             0.8334         estimate D2E/DX2
 !
  ! D21   D(3,4,5,6)             -1.5607         estimate D2E/DX2
 !
  ! D22   D(3,4,5,40)           178.2847         estimate D2E/DX2
 !
  ! D23   D(37,4,5,6)           178.6881         estimate D2E/DX2
 !
  ! D24   D(37,4,5,40)           -1.4665         estimate D2E/DX2
 !
  ! D25   D(3,4,37,12)           -4.3163         estimate D2E/DX2
 !
  ! D26   D(3,4,37,15)         -109.259          estimate D2E/DX2
 !
  ! D27   D(3,4,37,24)           76.3234         estimate D2E/DX2
 !
  ! D28   D(3,4,37,31)          155.0742         estimate D2E/DX2
 !
  ! D29   D(3,4,37,33)          -91.0337         estimate D2E/DX2
 !
  ! D30   D(5,4,37,12)          175.4508         estimate D2E/DX2
 !
  ! D31   D(5,4,37,15)           70.508          estimate D2E/DX2
 !
  ! D32   D(5,4,37,24)         -103.9096         estimate D2E/DX2
 !
  ! D33   D(5,4,37,31)          -25.1587         estimate D2E/DX2
 !
  ! D34   D(5,4,37,33)           88.7334         estimate D2E/DX2
 !
  ! D35   D(4,5,6,1)             -0.5564         estimate D2E/DX2
 !
  ! D36   D(4,5,6,41)           179.5725         estimate D2E/DX2
 !
  ! D37   D(40,5,6,1)           179.5984         estimate D2E/DX2
 !
  ! D38   D(40,5,6,41)           -0.2727         estimate D2E/DX2
 !
  ! D39   D(3,7,8,9)           -178.1978         estimate D2E/DX2
 !
  ! D40   D(3,7,8,42)             1.8514         estimate D2E/DX2
 !
  ! D41   D(12,7,8,9)             1.058          estimate D2E/DX2
 !
  ! D42   D(12,7,8,42)         -178.8928         estimate D2E/DX2
 !
  ! D43   D(3,7,12,11)          176.4774         estimate D2E/DX2
 !
  ! D44   D(3,7,12,37)           -4.2992         estimate D2E/DX2
 !
  ! D45   D(8,7,12,11)           -2.8631         estimate D2E/DX2
 !
  ! D46   D(8,7,12,37)          176.3603         estimate D2E/DX2
 !
  ! D47   D(7,8,9,10)             0.7724         estimate D2E/DX2
 !
  ! D48   D(7,8,9,43)          -179.433          estimate D2E/DX2
 !
  ! D49   D(42,8,9,10)         -179.2769         estimate D2E/DX2
 !
  ! D50   D(42,8,9,43)            0.5178         estimate D2E/DX2
 !
  ! D51   D(8,9,10,11)           -1.0349         estimate D2E/DX2
 !
  ! D52   D(8,9,10,44)          179.0599         estimate D2E/DX2
 !
  ! D53   D(43,9,10,11)         179.1703         estimate D2E/DX2
 !
  ! D54   D(43,9,10,44)          -0.7349         estimate D2E/DX2
 !
  ! D55   D(9,10,11,12)          -0.6063         estimate D2E/DX2
 !
  ! D56   D(9,10,11,45)         179.6381         estimate D2E/DX2
 !
  ! D57   D(44,10,11,12)        179.2991         estimate D2E/DX2
 !
  ! D58   D(44,10,11,45)         -0.4565         estimate D2E/DX2
 !
  ! D59   D(10,11,12,7)           2.5514         estimate D2E/DX2
 !
  ! D60   D(10,11,12,37)       -176.5859         estimate D2E/DX2
 !
  ! D61   D(45,11,12,7)        -177.6916         estimate D2E/DX2
 !
  ! D62   D(45,11,12,37)          3.1711         estimate D2E/DX2
 !
  ! D63   D(7,12,37,4)            4.6629         estimate D2E/DX2
 !
  ! D64   D(7,12,37,15)          79.6027         estimate D2E/DX2
 !
  ! D65   D(7,12,37,24)         -81.793          estimate D2E/DX2
 !
  ! D66   D(7,12,37,31)        -127.9971         estimate D2E/DX2
 !
  ! D67   D(7,12,37,33)         161.4832         estimate D2E/DX2
 !
  ! D68   D(11,12,37,4)        -176.1211         estimate D2E/DX2
 !
  ! D69   D(11,12,37,15)       -101.1813         estimate D2E/DX2
 !
  ! D70   D(11,12,37,24)         97.423          estimate D2E/DX2
 !
  ! D71   D(11,12,37,31)         51.2189         estimate D2E/DX2
 !
  ! D72   D(11,12,37,33)        -19.3009         estimate D2E/DX2
 !
  ! D73   D(19,13,15,16)          1.9121         estimate D2E/DX2
 !
  ! D74   D(19,13,15,37)       -177.4276         estimate D2E/DX2
 !
  ! D75   D(46,13,15,16)       -178.3742         estimate D2E/DX2
 !
  ! D76   D(46,13,15,37)          2.2861         estimate D2E/DX2
 !
  ! D77   D(15,13,19,18)          0.1582         estimate D2E/DX2
 !
  ! D78   D(15,13,19,50)       -179.8245         estimate D2E/DX2
 !
  ! D79   D(46,13,19,18)       -179.5559         estimate D2E/DX2
 !
  ! D80   D(46,13,19,50)          0.4614         estimate D2E/DX2
 !
  ! D81   D(24,14,20,21)          0.6983         estimate D2E/DX2
 !
  ! D82   D(24,14,20,51)       -179.3042         estimate D2E/DX2
 !
  ! D83   D(47,14,20,21)       -179.5631         estimate D2E/DX2
 !
  ! D84   D(47,14,20,51)          0.4344         estimate D2E/DX2
 !
  ! D85   D(20,14,24,23)         -1.6299         estimate D2E/DX2
 !
  ! D86   D(20,14,24,37)        177.4768         estimate D2E/DX2
 !
  ! D87   D(47,14,24,23)        178.6317         estimate D2E/DX2
 !
  ! D88   D(47,14,24,37)         -2.2616         estimate D2E/DX2
 !
  ! D89   D(13,15,16,17)         -2.9201         estimate D2E/DX2
 !
  ! D90   D(13,15,16,25)        176.3928         estimate D2E/DX2
 !
  ! D91   D(37,15,16,17)        176.4667         estimate D2E/DX2
 !
  ! D92   D(37,15,16,25)         -4.2204         estimate D2E/DX2
 !
  ! D93   D(13,15,37,4)          -3.9612         estimate D2E/DX2
 !
  ! D94   D(13,15,37,12)        -85.762          estimate D2E/DX2
 !
  ! D95   D(13,15,37,24)         13.7487         estimate D2E/DX2
 !
  ! D96   D(13,15,37,31)        106.3048         estimate D2E/DX2
 !
  ! D97   D(13,15,37,33)       -176.8073         estimate D2E/DX2
 !
  ! D98   D(16,15,37,4)         176.6616         estimate D2E/DX2
 !
  ! D99   D(16,15,37,12)         94.8608         estimate D2E/DX2
 !
  ! D100  D(16,15,37,24)       -165.6285         estimate D2E/DX2
 !
  ! D101  D(16,15,37,31)        -73.0725         estimate D2E/DX2
 !
  ! D102  D(16,15,37,33)          3.8155         estimate D2E/DX2
 !
  ! D103  D(15,16,17,18)          1.6733         estimate D2E/DX2
 !
  ! D104  D(15,16,17,48)       -178.2869         estimate D2E/DX2
 !
  ! D105  D(25,16,17,18)       -177.5515         estimate D2E/DX2
 !
  ! D106  D(25,16,17,48)          2.4883         estimate D2E/DX2
 !
  ! D107  D(15,16,25,33)          1.8669         estimate D2E/DX2
 !
  ! D108  D(15,16,25,36)       -177.3515         estimate D2E/DX2
 !
  ! D109  D(17,16,25,33)       -178.844          estimate D2E/DX2
 !
  ! D110  D(17,16,25,36)          1.9376         estimate D2E/DX2
 !
  ! D111  D(16,17,18,19)          0.3859         estimate D2E/DX2
 !
  ! D112  D(16,17,18,49)       -179.8662         estimate D2E/DX2
 !
  ! D113  D(48,17,18,19)       -179.6538         estimate D2E/DX2
 !
  ! D114  D(48,17,18,49)          0.0941         estimate D2E/DX2
 !
  ! D115  D(17,18,19,13)         -1.2918         estimate D2E/DX2
 !
  ! D116  D(17,18,19,50)        178.6909         estimate D2E/DX2
 !
  ! D117  D(49,18,19,13)        178.9601         estimate D2E/DX2
 !
  ! D118  D(49,18,19,50)         -1.0572         estimate D2E/DX2
 !
  ! D119  D(14,20,21,22)          0.1994         estimate D2E/DX2
 !
  ! D120  D(14,20,21,52)       -179.5363         estimate D2E/DX2
 !
  ! D121  D(51,20,21,22)       -179.7981         estimate D2E/DX2
 !
  ! D122  D(51,20,21,52)          0.4662         estimate D2E/DX2
 !
  ! D123  D(20,21,22,23)         -0.2637         estimate D2E/DX2
 !
  ! D124  D(20,21,22,53)        179.6084         estimate D2E/DX2
 !
  ! D125  D(52,21,22,23)        179.4719         estimate D2E/DX2
 !
  ! D126  D(52,21,22,53)         -0.6559         estimate D2E/DX2
 !
  ! D127  D(21,22,23,24)         -0.6749         estimate D2E/DX2
 !
  ! D128  D(21,22,23,26)        179.135          estimate D2E/DX2
 !
  ! D129  D(53,22,23,24)        179.4534         estimate D2E/DX2
 !
  ! D130  D(53,22,23,26)         -0.7367         estimate D2E/DX2
 !
  ! D131  D(22,23,24,14)          1.5922         estimate D2E/DX2
 !
  ! D132  D(22,23,24,37)       -177.5619         estimate D2E/DX2
 !
  ! D133  D(26,23,24,14)       -178.2376         estimate D2E/DX2
 !
  ! D134  D(26,23,24,37)          2.6083         estimate D2E/DX2
 !
  ! D135  D(22,23,26,27)         -0.8766         estimate D2E/DX2
 !
  ! D136  D(22,23,26,31)        179.9837         estimate D2E/DX2
 !
  ! D137  D(24,23,26,27)        178.9457         estimate D2E/DX2
 !
  ! D138  D(24,23,26,31)         -0.194          estimate D2E/DX2
 !
  ! D139  D(14,24,37,4)         -69.3227         estimate D2E/DX2
 !
  ! D140  D(14,24,37,12)         16.6771         estimate D2E/DX2
 !
  ! D141  D(14,24,37,15)        -86.5779         estimate D2E/DX2
 !
  ! D142  D(14,24,37,31)        177.7462         estimate D2E/DX2
 !
  ! D143  D(14,24,37,33)        105.1351         estimate D2E/DX2
 !
  ! D144  D(23,24,37,4)         109.8103         estimate D2E/DX2
 !
  ! D145  D(23,24,37,12)       -164.1899         estimate D2E/DX2
 !
  ! D146  D(23,24,37,15)         92.5551         estimate D2E/DX2
 !
  ! D147  D(23,24,37,31)         -3.1208         estimate D2E/DX2
 !
  ! D148  D(23,24,37,33)        -75.7319         estimate D2E/DX2
 !
  ! D149  D(16,25,33,32)       -178.4094         estimate D2E/DX2
 !
  ! D150  D(16,25,33,37)          1.2375         estimate D2E/DX2
 !
  ! D151  D(36,25,33,32)          0.8356         estimate D2E/DX2
 !
  ! D152  D(36,25,33,37)       -179.5174         estimate D2E/DX2
 !
  ! D153  D(16,25,36,35)        177.7168         estimate D2E/DX2
 !
  ! D154  D(16,25,36,61)         -1.9029         estimate D2E/DX2
 !
  ! D155  D(33,25,36,35)         -1.4432         estimate D2E/DX2
 !
  ! D156  D(33,25,36,61)        178.9371         estimate D2E/DX2
 !
  ! D157  D(23,26,27,28)       -177.1305         estimate D2E/DX2
 !
  ! D158  D(23,26,27,54)          2.76           estimate D2E/DX2
 !
  ! D159  D(31,26,27,28)          1.9263         estimate D2E/DX2
 !
  ! D160  D(31,26,27,54)       -178.1833         estimate D2E/DX2
 !
  ! D161  D(23,26,31,30)        176.8607         estimate D2E/DX2
 !
  ! D162  D(23,26,31,37)         -2.3386         estimate D2E/DX2
 !
  ! D163  D(27,26,31,30)         -2.2995         estimate D2E/DX2
 !
  ! D164  D(27,26,31,37)        178.5012         estimate D2E/DX2
 !
  ! D165  D(26,27,28,29)         -0.5549         estimate D2E/DX2
 !
  ! D166  D(26,27,28,55)        179.2756         estimate D2E/DX2
 !
  ! D167  D(54,27,28,29)        179.5546         estimate D2E/DX2
 !
  ! D168  D(54,27,28,55)         -0.6149         estimate D2E/DX2
 !
  ! D169  D(27,28,29,30)         -0.4896         estimate D2E/DX2
 !
  ! D170  D(27,28,29,56)        179.5205         estimate D2E/DX2
 !
  ! D171  D(55,28,29,30)        179.6799         estimate D2E/DX2
 !
  ! D172  D(55,28,29,56)         -0.31           estimate D2E/DX2
 !
  ! D173  D(28,29,30,31)          0.1888         estimate D2E/DX2
 !
  ! D174  D(28,29,30,57)       -179.7221         estimate D2E/DX2
 !
  ! D175  D(56,29,30,31)       -179.8213         estimate D2E/DX2
 !
  ! D176  D(56,29,30,57)          0.2678         estimate D2E/DX2
 !
  ! D177  D(29,30,31,26)          1.1405         estimate D2E/DX2
 !
  ! D178  D(29,30,31,37)       -179.7305         estimate D2E/DX2
 !
  ! D179  D(57,30,31,26)       -178.9489         estimate D2E/DX2
 !
  ! D180  D(57,30,31,37)          0.1801         estimate D2E/DX2
 !
  ! D181  D(26,31,37,4)         -78.9063         estimate D2E/DX2
 !
  ! D182  D(26,31,37,12)         48.9221         estimate D2E/DX2
 !
  ! D183  D(26,31,37,15)       -158.3303         estimate D2E/DX2
 !
  ! D184  D(26,31,37,24)          2.8636         estimate D2E/DX2
 !
  ! D185  D(26,31,37,33)        122.6246         estimate D2E/DX2
 !
  ! D186  D(30,31,37,4)         101.9167         estimate D2E/DX2
 !
  ! D187  D(30,31,37,12)       -130.2548         estimate D2E/DX2
 !
  ! D188  D(30,31,37,15)         22.4928         estimate D2E/DX2
 !
  ! D189  D(30,31,37,24)       -176.3133         estimate D2E/DX2
 !
  ! D190  D(30,31,37,33)        -56.5524         estimate D2E/DX2
 !
  ! D191  D(34,32,33,25)          0.2405         estimate D2E/DX2
 !
  ! D192  D(34,32,33,37)       -179.3802         estimate D2E/DX2
 !
  ! D193  D(58,32,33,25)       -179.7632         estimate D2E/DX2
 !
  ! D194  D(58,32,33,37)          0.6161         estimate D2E/DX2
 !
  ! D195  D(33,32,34,35)         -0.7295         estimate D2E/DX2
 !
  ! D196  D(33,32,34,59)        179.137          estimate D2E/DX2
 !
  ! D197  D(58,32,34,35)        179.2742         estimate D2E/DX2
 !
  ! D198  D(58,32,34,59)         -0.8593         estimate D2E/DX2
 !
  ! D199  D(25,33,37,4)         -20.7473         estimate D2E/DX2
 !
  ! D200  D(25,33,37,12)       -105.9007         estimate D2E/DX2
 !
  ! D201  D(25,33,37,15)         -2.8342         estimate D2E/DX2
 !
  ! D202  D(25,33,37,24)        173.4118         estimate D2E/DX2
 !
  ! D203  D(25,33,37,31)         99.3711         estimate D2E/DX2
 !
  ! D204  D(32,33,37,4)         158.8847         estimate D2E/DX2
 !
  ! D205  D(32,33,37,12)         73.7313         estimate D2E/DX2
 !
  ! D206  D(32,33,37,15)        176.7978         estimate D2E/DX2
 !
  ! D207  D(32,33,37,24)         -6.9562         estimate D2E/DX2
 !
  ! D208  D(32,33,37,31)        -80.9969         estimate D2E/DX2
 !
  ! D209  D(32,34,35,36)          0.1169         estimate D2E/DX2
 !
  ! D210  D(32,34,35,60)       -179.8004         estimate D2E/DX2
 !
  ! D211  D(59,34,35,36)       -179.7497         estimate D2E/DX2
 !
  ! D212  D(59,34,35,60)          0.333          estimate D2E/DX2
 !
  ! D213  D(34,35,36,25)          0.9309         estimate D2E/DX2
 !
  ! D214  D(34,35,36,61)       -179.4493         estimate D2E/DX2
 !
  ! D215  D(60,35,36,25)       -179.1518         estimate D2E/DX2
 !
  ! D216  D(60,35,36,61)          0.468          estimate D2E/DX2
 !
  ----------------------------------------------------------------------------
 ----
  Trust Radius=3.00D-01 FncErr=1.00D-07 GrdErr=1.00D-06
  Number of steps in this run= 366 maximum allowed number of steps= 366.
  GradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGrad
  Stoichiometry    C33H24IrN3
  Framework group  C1[X(C33H24IrN3)]
  Deg. of freedom   177
  Full point group                 C1      NOp   1
  Largest Abelian subgroup         C1      NOp   1
  Largest concise Abelian subgroup C1      NOp   1
                          Standard orientation:
  ---------------------------------------------------------------------
  Center     Atomic     Atomic              Coordinates (Angstroms)
  Number     Number      Type              X           Y           Z
  ---------------------------------------------------------------------
     1          6             0        3.567904   -2.253393   -2.381794
     2          6             0        3.577979   -2.096578   -1.030528
     3          6             0        2.385965   -1.404845   -0.361244
     4          6             0        1.353910   -0.925171   -1.099605
     5          6             0        1.320843   -1.115490   -2.620480
     6          6             0        2.364257   -1.748133   -3.222539
     7          6             0        2.238934   -1.201109    1.165468
     8          6             0        3.135502   -1.590421    2.100373
     9          6             0        2.792354   -1.336601    3.583135
    10          6             0        1.607130   -0.751536    3.897276
    11          6             0        0.648970   -0.335629    2.767042
    12          7             0        0.995540   -0.540188    1.542156
    13          6             0       -0.398653   -2.512048   -1.360619
    14          6             0        2.571724    1.497132    0.888649
    15          7             0       -0.952025   -1.650543   -0.560597
    16          6             0       -2.290349   -1.852842   -0.032497
    17          6             0       -3.050423   -2.909584   -0.386135
    18          6             0       -2.453262   -3.947066   -1.352305
    19          6             0       -1.187011   -3.765221   -1.804314
    20          6             0        3.428224    2.552255    0.861423
    21          6             0        3.070233    3.819461    0.048584
    22          6             0        1.896600    3.882180   -0.636876
    23          6             0        0.945427    2.676447   -0.592243
    24          6             0        1.258213    1.570292    0.094049
    25          6             0       -2.702959   -0.768369    0.948247
    26          6             0       -0.399892    2.604901   -1.286203
    27          6             0       -0.941179    3.601552   -2.019739
    28          6             0       -2.346636    3.389818   -2.601306
    29          6             0       -2.981740    2.214713   -2.367858
    30          6             0       -2.271584    1.117654   -1.534326
    31          7             0       -1.077392    1.335416   -1.064586
    32          6             0       -2.034706    1.340395    2.105353
    33          6             0       -1.776022    0.192851    1.114839
    34          6             0       -3.202925    1.364310    2.807059
    35          6             0       -4.264438    0.259324    2.597623
    36          6             0       -4.032905   -0.743360    1.711627
    37         77             0       -0.061288    0.015299    0.006010
    38          1             0        4.395196   -2.727288   -2.866784
    39          1             0        4.402257   -2.450068   -0.445236
    40          1             0        0.493008   -0.760077   -3.194695
    41          1             0        2.356476   -1.896537   -4.281250
    42          1             0        4.054510   -2.059131    1.820138
    43          1             0        3.474975   -1.619584    4.352336
    44          1             0        1.341764   -0.579618    4.919054
    45          1             0       -0.293817    0.122182    2.989944
    46          1             0        0.598333   -2.353105   -1.715580
    47          1             0        2.812570    0.621738    1.455305
    48          1             0       -4.044991   -3.025681   -0.006027
    49          1             0       -3.024235   -4.798947   -1.659392
    50          1             0       -0.737378   -4.482328   -2.461681
    51          1             0        4.350910    2.508065    1.401905
    52          1             0        3.748039    4.645084    0.022228
    53          1             0        1.641549    4.759962   -1.196017
    54          1             0       -0.405757    4.515326   -2.189792
    55          1             0       -2.817324    4.156817   -3.178016
    56          1             0       -3.964494    2.047000   -2.756177
    57          1             0       -2.761344    0.188172   -1.349083
    58          1             0       -1.306411    2.112434    2.243337
    59          1             0       -3.386520    2.152702    3.510205
    60          1             0       -5.182526    0.285125    3.149888
    61          1             0       -4.765376   -1.508352    1.552994
  ---------------------------------------------------------------------
  Rotational constants (GHZ):      0.1309462      0.1155067      0.1031387
 Sorry for multilpe posting.
 Enrico D'Ortenzio
 -----------------------------------------------------------------------------
 -----------------------------------------------------------------------------
 Sent to CCL by: Johannes Poms [poms|student.tugraz.at]
 > Sent to CCL by: "Enrico D Ortenzio"
 [enrico.dortenzio/a\hotmail.it]
 > Hello,
 > i'm new in computational chemistry and i'm learning to use Gaussian03.
 > For simplest calculations, i.e for smallest molecules, there is no
 problem...
 > but when I try to do TDDFT calculations on bigger molecules such as
 > poly(p-phenylene vinylene)or Iridium complexes such as Ir(ppy)3 i get
 > the following error:
 >
 > severe error message 2070
 >
 Post your full input/error log
 Normally this is just the generic error message
 "Severe error message #2070
 The processing of the last link ended abnormally. All processing has
 been aborted."
 So the actual error is in the link before this message!
 And the next time please post your request just once
 best
 Johannes