CCL:G: problem calculating NLMOs



Dear CCL subscribers,
 
I'm trying to calculate the NLMOs of a phosphorus cage compound using NBO3.1 implemented in Gaussianl. However, I receive the following error message:
 
NATURAL LOCALIZED MOLECULAR ORBITAL (NLMO) ANALYSIS:
 
 Highest occupied NBOs are not at the beginning of the NBO list;
 The NLMO program is not currently set up to handle this.
 Illegal range for read:  IUnit=  7 Address=      -256 Length=            -256 File length=         1574400.
 Error termination in NtrErr:
 NtrErr called > from NtrIO.
Has anyone experience with this problem?
 
Kind regards,
Robert
 

--
Dr. Robert Wolf
Institut für Anorganische und Analytische Chemie
WWU Münster

Corrensstraße 30
D-48149 Münster
Germany

http://www.uni-muenster.de/Chemie.ac/uhl/wolf.html

Tel.  +49 251 83-36090 (office) / -36070 (lab),
FAX +49 251 83-36660 (office Prof. Uhl)

 


Von: owner-chemistry+r.wolf==uni-muenster.de_+_ccl.net [mailto:owner-chemistry+r.wolf==uni-muenster.de_+_ccl.net] Im Auftrag von Narayan Chandra Bera ncbera05%a%gmail.com
Gesendet: Montag, 27. April 2009 22:14
An: Wolf, Robert
Betreff: CCL: Kindly solve my Turbomol problem

Dear Sir,
          I am a turbomol user, I am doing single point energy calculation of a molecule having 43 atoms, its charge is -1 and multiplicity is 1 at RI-MP2/aug-cc-pVTZ level . To perform this ri-mp2 calculation i did dscf calculation and all the necessary input through define comment, the dscf calculation has been performed successfully but problem arises in rimp2 calculation during calculation, after calculating some steps it stopped automatically without giving any error massage (please see below, i'm giving the last few lines). I cant understand whats the problem. Kindly help me. Waiting for your reply.

With best regards,
Narayan
    

 echeck from tr(Qit)
 mp2 energy difference between galoop and gamder=-0.1243449787580D-13

 -----------------------------------------------------
     prepare right hand side of z-vector equations
 -----------------------------------------------------

 total memory allocated for eval. of r.h.s. of z-vector equation :   51 MByte

   disc space (kbyte) allocation for  1 2e-integral file(s) :
   --------------------------------------------------------
   twoint                                                 0
   --------------------------------------------------------

 maximum number of buffers which may be written onto 2e-file(s) =         0


         0 2 e - integrals written in         0 blocks requiring       0 k-byte

         total  zprep  cpu-time :  4 hours 44 minutes and 58 seconds
         total  zprep wall-time :  4 hours 45 minutes and 18 seconds
 additional memory allocated for solution of z-vector equation :   17 MByte

          -------------------------------------------------
          -CPHF- contribution to MP2-Gradient via Z-vector
          -------------------------------------------------

   Requested convergence is     0.1000000000E-10  RMS
     and a residual norm of     0.1000000000E-02

      Iteration           RMS                   |R|

           1        0.6245080095E-06      0.2526108240E+00
           2        0.5572694041E-07      0.7545978248E-01
           3        0.1043855378E-07      0.3265901752E-01
           4        0.1252709341E-08      0.1131378984E-01
           5        0.1215664530E-09      0.3524437567E-02
           6        0.1871648610E-10      0.1382913790E-02
rimp2.out lines 777-821/821 (END)






--
**********************************************************
Dr. Narayan Chandra Bera
Postdoctoral Research Associate
USA
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