CCL:G: Problems with the massage command in Gaussian 03



 Sent to CCL by: Pedro Salvador [pedro.salvador\a/udg.edu]
 Hi,
 
the use of massage is not recommended. Use "-bq" instead for the atoms you wish to massage (see Counterpoise keyword). The key error message you got is "Spurious integrated density or basis function:" This is quite typical in ghost orbital calculations. Better use also guess=core.
 Hope it helps
 Pedro
 Roland Schaap rolandschaap(0)gmail.com wrote:
 
 Sent to CCL by: "Roland  Schaap" [rolandschaap . gmail.com]
 Hello,
 I have been running several jobs in Gaussian 03 using the massage command. All
 seemed to be doing fine untill one job ended in a very strange fashion, without
 showing an error message. The job was removed from the queu on the cluster
 therefore I assume it is terminated. Displayed below is the output which shows
 the basis sets etc. The job concerns the BSSE calculations on a
 4-methylimidazole and a porphirine ring containing a magnesium, to which the
 imidazole is oriented (to slightly shorten the message I left out the beginning
 of the output). Any help or suggestions would be appreciated!
 ******************************************
 Gaussian 03:  AM64L-G03RevD.01 13-Oct-2005
 
8-Dec-2007 ******************************************
 %NoSave
 %Chk=L173_B851_Cryst_BSSE1.chk
 %Mem=1024MB
 ----------------------------------------------------------------------
 # BLYP/6-311++G(d,p) SCF=Tight Population=minimal density=current Mass
 age
 ----------------------------------------------------------------------
 1/30=1,38=1/1;
 2/15=1,17=6,18=5,40=1/2;
 3/5=4,6=6,7=1111,10=10,11=2,16=1,25=1,30=1,74=402/1,2,3;
 4//1;
 5/5=2,32=2,38=5/2;
 6/7=2,8=2,9=2,10=2,22=-1,28=1/1;
 99/5=1,9=1/99;
 ----------------------------------------------------------------------
 BSSE Calculations on crystal structure LHis-173 coordinated to BChl-85
 1, both wi
 ----------------------------------------------------------------------
 Symbolic Z-matrix:
 Charge =  0 Multiplicity = 1
 
C 19.271 92.374 42.96 N 19.809 93.421 42.247 C 20.991 93.721 42.753 N 21.23 92.907 43.769 C 20.159 92.051 43.933 C 20.059 91.094 45.084 C 20.377 89.632 44.735 N 20.056 88.778 45.88 C 21.865 89.465 44.431 O 22.287 89.506 43.273 O 22.6928 89.27111 45.4868 Mg 19.235 94.878 40.16 N 21.263 94.917 39.705 C 21.9 93.952 39.002 C 23.258 94.272 38.815 C 23.503 95.572 39.472 C 22.189 95.883 40.023 C 21.269 92.818 38.522 C 19.957 92.396 38.574 N 18.92 93.077 39.166 C 17.735 92.338 38.931 C 18.013 91.07 38.146 C 19.486 91.139 37.961 C 16.494 92.825 39.396 C 16.303 94.009 40.131 C 14.965 94.304 40.5 C 14.184 93.246 39.963 C 15.074 92.25 39.222 N 17.235 94.935 40.538 C 16.53 95.894 41.219 C 15.17 95.588 41.254 C 17.061 97.027 41.782 C 18.371 97.411 41.751 C 18.845 98.678 42.354 C 20.332 98.694 42.065 C 20.543 97.41 41.296 N 19.393 96.689 41.14 C 18.127 99.892 41.643 C 18.879 101.217 41.51199 C 21.742 97.011 40.78099 C 21.179 98.712 43.33899 C 14.003 96.39 41.909 C 14.711 90.811 39.666 O 15.402 90.186 40.472 O 12.94 93.216 40.106 C 20.047 89.979 38.812 C 17.283 91.22 36.791 C 17.38 90.066 35.811 C 16.074 89.294 35.728 O 15.335 89.236 36.704 C 24.782 96.428 39.567 O 24.738 97.512 40.179 C 24.16 93.274 37.992 C 26.079 95.931 38.869 O 15.774 88.727 34.635 O 13.649 90.365 39.092 C 13.077 89.066 39.294 H 22.03636 92.98081 44.39635 H 20.26402 87.80184 45.64661 H 19.06072 88.87033 46.10625 H 19.77938 89.3494 43.85072 H 20.838 91.40784 45.80511 H 19.05227 91.1556 45.52526 H 18.31263 91.89481 42.77678 H 21.65525 94.50401 42.39571 H 23.60579 89.18329 45.12267 H 21.93726 92.12544 38.00359 H 22.54572 97.71577 40.99707 H 16.36618 97.6884 42.30767 H 17.68927 90.12512 38.61237 H 19.78599 91.0863 36.89885 H 19.63443 89.02342 38.44797 H 19.76052 90.12578 39.86784 H 21.14608 89.95979 38.72909 H 17.82765 92.03547 36.2898 H 16.22038 91.4621 36.9703 H 18.1649 89.37541 36.171 H 17.64241 90.45404 34.81101 H 14.9079 88.26986 34.7293 H 23.7521 93.16543 36.96922 H 24.1691 92.29113 38.4895 H 25.1847 93.66595 37.93759 H 25.89722 95.828 37.78844 H 26.3696 94.95626 39.28675 H 26.89071 96.66063 39.03823 H 20.63998 99.60071 41.51489 H 18.63088 98.75716 43.4368 H 22.24661 98.62902 43.07184 H 20.89393 97.86285 43.98091 H 21.0079 99.65762 43.88166 H 17.31342 100.14124 42.34716 H 17.76386 99.57451 40.64792 H 19.80386 101.05897 40.92952 H 19.13702 101.59442 42.51575 H 18.24002 101.95319 40.99555 H 13.94421 97.39449 41.45186 H 14.1876 96.4894 42.9943 H 13.063 95.862 41.747 H 14.94568 92.13178 38.1348 H 12.81024 88.94419 40.35099 H 13.80869 88.29496 39.0094 H 12.17464 88.96204 38.67326
 Symmetry turned off by external request.
 Stoichiometry    C41H45MgN7O8
 Framework group  C1[X(C41H45MgN7O8)]
 Deg. of freedom   300
 Full point group                 C1
 
Z-Matrix orientation: ---------------------------------------------------------------------
 Center     Atomic     Atomic              Coordinates (Angstroms)
 Number     Number      Type              X           Y           Z
 ---------------------------------------------------------------------
    1          6             0       19.271000   92.374001   42.960000
    2          7             0       19.808999   93.421001   42.247000
    3          6             0       20.990999   93.721001   42.753000
    4          7             0       21.230001   92.907001   43.769000
    5          6             0       20.159001   92.051001   43.933000
    6          6             0       20.059001   91.094001   45.084000
    7          6             0       20.377000   89.632001   44.734999
    8          7             0       20.056001   88.778001   45.879998
    9          6             0       21.865000   89.465001   44.430999
   10          8             0       22.287000   89.506001   43.272999
   11          8             0       22.692801   89.271109   45.486803
   12         12             0       19.234999   94.878001   40.160000
   13          7             0       21.262999   94.917001   39.704999
   14          6             0       21.899999   93.952001   39.001999
   15          6             0       23.257999   94.272002   38.814998
   16          6             0       23.502999   95.572002   39.471997
   17          6             0       22.188999   95.883001   40.022999
   18          6             0       21.268999   92.818001   38.521999
   19          6             0       19.957000   92.396001   38.574000
   20          7             0       18.920000   93.077000   39.166000
   21          6             0       17.735000   92.338000   38.931000
   22          6             0       18.012999   91.070000   38.146000
   23          6             0       19.485999   91.139001   37.961000
   24          6             0       16.494000   92.825000   39.396000
   25          6             0       16.303000   94.009001   40.131000
   26          6             0       14.965000   94.304001   40.500001
   27          6             0       14.184000   93.246001   39.963001
   28          6             0       15.074000   92.250000   39.222001
   29          7             0       17.235000   94.935001   40.537999
   30          6             0       16.529999   95.894001   41.218999
   31          6             0       15.169999   95.588001   41.254000
   32          6             0       17.061000   97.027001   41.781999
   33          6             0       18.371000   97.411001   41.750998
   34          6             0       18.845001   98.678001   42.353998
   35          6             0       20.332001   98.694000   42.064995
   36          6             0       20.543000   97.410000   41.295996
   37          7             0       19.393000   96.689000   41.139998
   38          6             0       18.127001   99.892001   41.642998
   39          6             0       18.879001  101.217000   41.511995
   40          6             0       21.741998   97.011001   40.780995
   41          6             0       21.179003   98.712001   43.338995
   42          6             0       14.002999   96.390001   41.908999
   43          6             0       14.711000   90.811001   39.666002
   44          8             0       15.402000   90.186001   40.472001
   45          8             0       12.940000   93.216001   40.106001
   46          6             0       20.046999   89.979001   38.811999
   47          6             0       17.282999   91.220000   36.791000
   48          6             0       17.379999   90.066000   35.811000
   49          6             0       16.073998   89.294001   35.728000
   50          8             0       15.334998   89.236001   36.704000
   51          6             0       24.781998   96.428002   39.566996
   52          8             0       24.737999   97.512002   40.178996
   53          6             0       24.159999   93.274002   37.991997
   54          6             0       26.078998   95.931002   38.868997
   55          8             0       15.773998   88.727000   34.635000
   56          8             0       13.648999   90.365001   39.092002
   57          6             0       13.076999   89.066000   39.294002
   58          1             0       22.036365   92.980806   44.396346
   59          1             0       20.264019   87.801838   45.646613
   60          1             0       19.060718   88.870326   46.106245
   61          1             0       19.779380   89.349398   43.850724
   62          1             0       20.838005   91.407837   45.805111
   63          1             0       19.052273   91.155596   45.525263
   64          1             0       18.312631   91.894815   42.776782
   65          1             0       21.655253   94.504015   42.395712
   66          1             0       23.605791   89.183286   45.122674
   67          1             0       21.937258   92.125442   38.003592
   68          1             0       22.545715   97.715768   40.997069
   69          1             0       16.366180   97.688397   42.307672
   70          1             0       17.689271   90.125120   38.612370
   71          1             0       19.785994   91.086298   36.898852
   72          1             0       19.634432   89.023422   38.447970
   73          1             0       19.760517   90.125785   39.867837
   74          1             0       21.146080   89.959790   38.729087
   75          1             0       17.827653   92.035466   36.289797
   76          1             0       16.220378   91.462103   36.970298
   77          1             0       18.164896   89.375412   36.171000
   78          1             0       17.642407   90.454039   34.811010
   79          1             0       14.907896   88.269862   34.729299
   80          1             0       23.752104   93.165433   36.969222
   81          1             0       24.169100   92.291131   38.489500
   82          1             0       25.184703   93.665949   37.937587
   83          1             0       25.897221   95.827995   37.788439
   84          1             0       26.369598   94.956258   39.286750
   85          1             0       26.890708   96.660629   39.038230
   86          1             0       20.639979   99.600714   41.514887
   87          1             0       18.630877   98.757156   43.436798
   88          1             0       22.246608   98.629020   43.071840
   89          1             0       20.893933   97.862851   43.980912
   90          1             0       21.007902   99.657617   43.881661
   91          1             0       17.313421  100.141242   42.347155
   92          1             0       17.763863   99.574508   40.647920
   93          1             0       19.803863  101.058973   40.929524
   94          1             0       19.137023  101.594420   42.515747
   95          1             0       18.240023  101.953192   40.995547
   96          1             0       13.944210   97.394490   41.451860
   97          1             0       14.187603   96.489402   42.994300
   98          1             0       13.062999   95.862000   41.746999
   99          1             0       14.945676   92.131782   38.134799
  100          1             0       12.810237   88.944195   40.350985
  101          1             0       13.808685   88.294955   39.009401
  102          1             0       12.174645   88.962037   38.673256
 ---------------------------------------------------------------------
 Rotational constants (GHZ):      0.0482690      0.0340364      0.0299106
 Standard basis: 6-311++G(d,p) (5D, 7F)
 The nuclear charge for atom    1 has been changed to Z=  0   0.000000
 The nuclear charge for atom    2 has been changed to Z=  0   0.000000
 The nuclear charge for atom    3 has been changed to Z=  0   0.000000
 The nuclear charge for atom    4 has been changed to Z=  0   0.000000
 The nuclear charge for atom    5 has been changed to Z=  0   0.000000
 The nuclear charge for atom    6 has been changed to Z=  0   0.000000
 The nuclear charge for atom    7 has been changed to Z=  0   0.000000
 The nuclear charge for atom    8 has been changed to Z=  0   0.000000
 The nuclear charge for atom    9 has been changed to Z=  0   0.000000
 The nuclear charge for atom   10 has been changed to Z=  0   0.000000
 The nuclear charge for atom   11 has been changed to Z=  0   0.000000
 The nuclear charge for atom   58 has been changed to Z=  0   0.000000
 The nuclear charge for atom   59 has been changed to Z=  0   0.000000
 The nuclear charge for atom   60 has been changed to Z=  0   0.000000
 The nuclear charge for atom   61 has been changed to Z=  0   0.000000
 The nuclear charge for atom   62 has been changed to Z=  0   0.000000
 The nuclear charge for atom   63 has been changed to Z=  0   0.000000
 The nuclear charge for atom   64 has been changed to Z=  0   0.000000
 The nuclear charge for atom   65 has been changed to Z=  0   0.000000
 The nuclear charge for atom   66 has been changed to Z=  0   0.000000
 Integral buffers will be    131072 words long.
 Raffenetti 2 integral format.
 Two-electron integral symmetry is turned off.
  1577 basis functions,  2471 primitive gaussians,  1634 cartesian basis
 functions
   167 alpha electrons      167 beta electrons
       nuclear repulsion energy      5908.7664887872 Hartrees.
 NAtoms=  102 NActive=  102 NUniq=  102 SFac= 7.50D-01 NAtFMM=   80 NAOKFM=T
 Big=T
 One-electron integrals computed using PRISM.
 NBasis=  1577 RedAO= T  NBF=  1577
 NBsUse=  1557 1.00D-06 NBFU=  1557
 Harris functional with IExCor=  402 diagonalized for initial guess.
 ExpMin= 1.46D-02 ExpMax= 4.39D+04 ExpMxC= 1.51D+03 IAcc=3 IRadAn=         5
 AccDes= 0.00D+00
 HarFok:  IExCor= 402 AccDes= 0.00D+00 IRadAn=         5 IDoV=1
 ScaDFX=  1.000000  1.000000  1.000000  1.000000
 Warning:  off-atom basis functions, so minimal bfn integration tests in XC
 quadrature.
 Requested convergence on RMS density matrix=1.00D-08 within 128 cycles.
 Requested convergence on MAX density matrix=1.00D-06.
 Requested convergence on             energy=1.00D-06.
 No special actions if energy rises.
 Spurious integrated density or basis function:
 NE=  334 NElCor=    0 El error=8.92D+01 rel=2.67D-01 Tolerance=1.00D-03
 Shell    61     absolute error=3.51D+02              Tolerance=no limit
 Shell    61       signed error=3.51D+02              Tolerance=no limit
 PGFIO-F-235/formatted write/unit=6/edit descriptor does not match item type.
 File name = stdout     formatted, sequential access   record = 9
 In source file caldsu.f, at line number 952>