From chemistry-request- at -server.ccl.net Wed Aug 1 15:47:11 2001 Received: from hotmail.com ([64.4.37.25]) by server.ccl.net (8.11.0/8.11.0) with ESMTP id f71JlB507121 for ; Wed, 1 Aug 2001 15:47:11 -0400 Received: from mail pickup service by hotmail.com with Microsoft SMTPSVC; Wed, 1 Aug 2001 12:47:06 -0700 Received: from 66.81.51.229 by pv2fd.pav2.hotmail.msn.com with HTTP; Wed, 01 Aug 2001 19:47:06 GMT X-Originating-IP: [66.81.51.229] From: "Yuan-Yuan chen" To: chemistry: at :ccl.net Subject: Pericyclic additions Date: Wed, 01 Aug 2001 15:47:06 -0400 Mime-Version: 1.0 Content-Type: text/plain; format=flowed Message-ID: X-OriginalArrivalTime: 01 Aug 2001 19:47:06.0861 (UTC) FILETIME=[BEB539D0:01C11AC2] Hi, every one There are two recent papers of contradictory opinions on the mechanism of Diels-Alder reactions if you are interested: 1. Tetrahedron Lett. 2001, 42, 5077. “Merging of 4+2 and 2+4 cycloadditon paths in the regiospecific dimerization of methacrolein. A case of concerted crypto-diradical cycloaddition” 2. http://preprint.chemweb.com/orgchem/0107002 “Collision-induced electron reorganization as the general mechanism of concerted cycloaddition reactions”. Yuan-Yuan _________________________________________________________________ Get your FREE download of MSN Explorer at http://explorer.msn.com/intl.asp